Directives for the Use of Prussic Acid
(Zyklon) for the Destruction of Vermin (Disinfestation)
Translation of Document No. NI-9912 Office of Chief Counsel of War
Crimes
I. PROPERTIES OF PRUSSIC ACID (HYDROCYANIC ACID)
Prussic acid is a gas which is generated by evaporation
- Boiling point: 25 degrees Centigrade
- Freezing point: -15 degrees Centigrade
- Specific gravity: 0-69
- Steam density: 0-97 (Air: 1-0)
- The liquid evaporates easily.
- Liquid: transparent, colourless.
- Smell: peculiar, repulsively sweet.
- Extradordinarily great penetrative powers.
- Prussic acid is soluble in water.
Danger of explosion: 75g. prussic acid 1 cbm air. (Normal application
approx. 8-10 g. per cbm, therefore not explosive). Prussic acid may
not be brought into contact with an open flame, glowing wires, etc.,
because then it burns up slowly and loses all its effectiveness (carbonic
acid, water, and nitrogen are formed).
Toxic effect on warm-blooded animals: Since prussic acid has
practically no indicative irritant effect it is highly toxic and very
dangerous. Prussic acid is one of the most powerful poisons. 1mg. per
kg. of body weight is sufficient to kill a human being. Women and children
are generally more susceptible than men. Very small amounts of prussic
acid do not harm the human body, even if breathed continuously. Birds
and fishes are particularly susceptible to prussic acid.
Toxic effect on insects: The effects of prussic acid on insects
do not depend on the temperature to the same extent as that of other
gases, that is, it is also effective in low temperatures (even at 5
degrees Centigrade). The eggs of many insects, particularly bugs and
lice, are more susceptible than the full-grown insects.
Toxic effects on plants: The degree of toxicity depends on the
type of vegetation on the plants. Plants with thick leaves are less
susceptible than those with thin ones. Mildew and dry-rot are not killed
by prussic acid. Prussic acid does not destroy bacteria.
II. METHOD OF USING PRUSSIC ACID
ZYKLON is the absorption of a mixture of prussic acid and an irritant
by a carrier. Wood fibre discs, a reddish brown granular mass (diagriess
- Dia gravel) or small blue cubes (Erco) are used as carriers.
Apart from serving its purpose as indicator, this irritant also has
the advantage of stimulating the respiration of insects. Prussic acid
and the irritant are generated through simple evaporation. Zyklon will
keep for 3 months. Use damaged cans first. The contents of a can must
all be used up at once. Liquid prussic acid damages polish, laquer,
paint, etc. Gaseous prussic acid is harmless. The toxicity of the prussic
acid remains unchanged by the addition of the irritant; the danger connected
with it is however considerably decreased.
Zykon can be rendered inoffensive by combustion.
III. POSSIBLE POISONING
- Slight Poisoning:
Dizziness, headache, vomiting, general
feeling of sickness, etc. All these symptoms pass if one immediately
gets out into the fresh air. Alcohol reduces resistance to prussic
acid gassing, therefore do not drink alcohol before fumigation.
Prescribe: 1 tablet Cardiazol or Veriazol in order to prevent heart
disorders, if necessary repeat after 1-3 hours.
- Severe poisoning:
The affected person will collapse suddenly
and faint. First aid: fresh air, remove gas mask, loosen clothing,
apply artificial respiration. Lobelin, intermuscular 0-01 g. Do
not give camphor injections.
- Poisoning through the skin:
Symptoms as for 1. Treat the
same way.
- Stomach poisoning:
Treat with Lobelin intermuscular 0-01
g., ferrous sulphate, burnt magnesia.
IV. PROTECTION AGAINST GAS
When fumigating with Zyklon use only special filters, e.g.: the filter
insert "J" (blue-brown) of the Auergesellschaft Berlin or of the Draegerwerke,
Luebeck. Should gas seep through the mask, leave the building immediately
and change filters after also checking the mask and its fit to see whether
they are tight. The filter insert is exhausted if gas enters through
the mask. If using filter "J", first move around in the open air for
approx. 2 minutes so that a certain amount of moisture from the breath
may gather in the filter insert. Under no circumstances should filters
be changed inside gas-filled rooms.
V. PERSONNEL
A disinfestation squad consisting of at least 2 members is employed
for each disinfestation project. The fumigation chief is responsible
for the fumigation. His particular duties are inspection, airing, release
and safety measures. The fumigation chief is to appoint a deputy in
case has has to leave. The orders of the fumigation chief are to be
followed without delay.
Untrained persons or persons who are trained but who do not yet hold
a certificate may not be called upon to work on gassing operations,
nor may they be taken into gas-filled rooms. The fumigation chief must
also know where to contact his personnel. Every person must at all times
be able to prove he has official authorization for the use of prussic
acid for extermination purposes.
VI. EQUIPMENT
Each member must at all times carry with him:
- His own gas mask.
- At least 2 special filter inserts against Zyklon prussic acid.
- The leaflet First Aid for Prussic Acid Poisoning.
- Work order.
- Authorization certificate.
Each disinfestation squad must at all times carry:
- At least 3 special inserts as extra stock.
- 1 gas detector.
- 1 instrument for injecting Lobelin.
- Lobelin 0-01 g. ampules.
- Cardiazol, Veriazol tablets.
- 1 lever or pickhammer for opening cans of Zyklon.
- Warning signs as per regulation.
- Material for sealing.
- Sheets of paper to serve as pads.
- Flashlight.
All equipment to be kept clean and in good order at all times. Damage
to equipment is to be repaired at once.
VII. PLANNING FUMIGATIONS
- Can the fumigation be carried out at all?
- Type of building and situation.
- Condition of roof.
- Condition of windows.
- Presence of heating shafts, air shafts, breaks in the walls,
etc.
- Determine the kind of vermin to be exterminated.
- Calculate the space. (Do not rely on drawings but take measurements
yourself. Take only outside measurements, include walls).
- Prepare personnel. (Remove domestic animals, plants, food and
drink, undevelped photographic plates, and gas mask filters).
- Find which openings will be particularly difficult to seal.
(Air shafts, drains, large opening which have been boarded up, roofs).
- Settle necessary safety measures. (Guarding, work detachment
for sealing).
- Fix the date for the fumigation and the time for clearing the
building.
- If necessary, arrange safety measures for the neighbourhood
in good time.
- Notify authorities.
VIII. PREPARATION FOR FUMIGATION
- Seal.
- Open all doors, closets, drawers, etc.
- Pull bedding apart.
- Remove all liquids (remains of coffee, washing water, etc.).
- Remove all food.
- Remove all plants and domestic animals (aquaria, etc.).
- Remove all undeveloped photographic plates and films.
- Remove adhesive plaster, all medical supplies, whether open
or in paper bags (particularly coal).
- Remove all gas mask filters.
- Prepare to check on results.
- Clear out personnel.
- Take over keys (every door key).
IX. THE STRENGTH OF THE GAS AND THE TIME REQUIRED FOR IT TO TAKE
EFFECT DEPENDS ON:
For inside temperatures of more than 5 degrees Centigrade, it is customary
to use 8 g. prussic acid per cbm.
Time needed to take effect: 16 hours, unless there are circumstances
such as a closed-in type of building, which requires less time. If the
weather is warm it is possible to reduce this to a minimum of 6 hours.
The period is to be extended to at least 32 hours if the temperature
is below 5 degrees Centigrade.
The strength and time as above are to be applied in the case of :bugs,
lice, fleas, etc. with eggs, larvae and chrysalises.
For clothers-moths: temperatures above 10 degrees Centigrade, 16 g.
per cbm and 24 hours to take effect.
For Flour-moths: same as for bugs.
X. FUMIGATION OF A BUILDING
- Check everybody has left the building.
- Unpack boxes of Zyklon. Make the appropriate amount ready for
each floor.
- Distribute the cans. One man to go into the building and receive
the cans which have been brought up the work detachment and to distribute
them. (Have them put next to the pads).
- Dismiss the work detachment.
- Post the guard. Fumigation chief to instruct the guard.
- Check that sealing and clearing have been completed.
- Put on gas masks.
- Open the cans and pour out the contents. The contents are to
be spread thinly so that the Zyklon can evaporate quickly and the
necessary density of gas can be achieved as soon as possible. This
process is to start on the top floor, but the cellar is dealt with
before the ground floor, should the cellar have no exit. Rooms that
have been dealt with should as far as possible not be re-entered.
This processing is to be done slowly and calmly. The staircase particularly
should only be used slowly. The processing may only be interrupted
in an emergency.
- The exit door to be locked, sealed (do not forget the keyhole)
and its key handed over to the fumigation chief.
- On the door fix a warning with the legend: Danger - Poison
Gas. Danger to Life, No Admittance. This warning sign is
to be in several languages if necessary, and in any case it must
be marked with at least one death's head, clearly visible.
- Gas masks, apparatus for resuscitation and gas detectors are
to be kept available at all times. Every member of the fumigation
squad must know where these objects are located.
- At least 1 member of the fumigation squad must always remain
near the building which is being fumigated. The guard must be notified
of his position.
XI. AIRING
The airing is connected with the greatest danger for those participating
and others. Therefore, it must be carried out particularly carefully
and a gas mask should always be worn. The airing should take place according
to the following principles: pure air should always be within reach
in the shortest possible time and the gas should flow out to that side
where it cannot endanger people who are not participating. Should the
airing be difficult, one trained man should remain in front of the building
in order to watch how the gas is blowing away.
- Take care to see that no strangers remain in the vicinity of
the building.
- Post the guards in such a way that they are not annoyed by the
gas as it blows out, but can still watch the entrances to the building.
- Put on a gas mask.
- Enter the building. Close door, but do not lock it.
- First open the windows on that side of the building where there
is no wind. Air floor by floor. Start on the ground floor and after
each floor take at least 10 minutes rest.
- The doors leading to the corridor, connecting doors between
rooms and windows must be opened in each room. Should there be difficulty
in opening any of the windows they should only be opened after most
of the gas has blown away.
- Partitions and other methods used to seal the room which cannot
be replaced quickly should only be removed after most of the gas
has blown away.
- Care should be taken to see that the heating system and water
pipes do not freeze should there be a frost or danger of it.
- Rooms with valuable contents, such as clothing stores, etc.
may be locked again as soon as the windows have been opened.
- Windows and doors which have been opened should be fastened
in such a way that they cannot slam.
- Covers in chimneys may be removed after the provisional release
of the building.
- The airing should continue for at least 20 hours.
- The Guard should remain near the building during the whole of
this time.
XII. PROVISIONAL RELEASE
A fumigated room may be released provisionally as soon as the paper
strip of the gas detector is of a lighter blue than the centre colour
pattern, when the doors and windows are open. Only work connected with
the airing and clearing up may be done in the rooms which have been
provisionally released. Under no circumstances may anyone rest or sleep
in these rooms. The doors and windows must be left open all the time.
XIII. CLEARING UP AFTER PROVISIONAL RELEASE
- Remove remains of Zyklon from the fumigated rooms. They should
generally be sent back to the factory in the same way as cans and
boxes. Before boxes are sent back from the fumigated rooms the incription
Poison must be removed from them. Damp, wet or soiled remains
as well as damaged cans may not be sent back under any circumstances.
They may be thrown on a rubbish or slag heap, but may never be emptied
into drains.
- Mattresses, straw palliasses, pillows upholstered furniture
and similar items must be shaken or beaten for at least one hour
in the open air (if rainy, at least 2 hours in the hall) under the
supervision of the fumigation chief or his assistant.
- If possible, the stuffing of straw palliasses should be changed.
The old stuffing may not, however, be burnt, but may be reused after
it has been aired for a further period.
- Should the chimneys be covered from above, these coverings must
be removed carefully since other wise there is a danger that the
fires in the stoves and hearths will not have sufficient draught,
which may cause carbon-monoxide poisoning.
- After the final release has been made, two copies of a fumigation
report are to be filled-in in the prescribed manner. The following
points in particular should be shown:
- Volume of fumigated rooms.
- Amount of Zyklon used.
- Name of fumigation chief.
- Names of other personnel.
- Time required for gas to take effect.
- Time at which disinfested rooms were released.
XIV. FINAL RELEASE
- Under no circumstances less than 21 hours after airing was started.
- All items removed for beating are to be taken back into the
room.
- Doors and windows to be closed for one hour.
- In rooms with heating facilities a temperature of at least 15
degrees Centigrade must be produced.
- Gas detecting. The paper strip may not show a darker blue than
the lightest colour, even between blankets and mattresses which
have been place on top of each other, or in rooms which are not
easily accessible and which it is difficult to air. Should this
not be the case, airing must be continued and the check for gas
repeated after a few hours.
- The check for gas must be made in each room of buildings which
are again to be used as sleeping accomodation as soon as possible.
Under no circumstances may anyone sleep in a room which has been
fumigated in the night following fumigation. The windows must always
remain open during the first night that the room is used again.
- The fumigation chief or his deputy may not leave the building
until the very last room has been finally released.
Issued by the Health Institution of the Protectorate of Bohemia and
Moravia in Prague.
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